CHEM V101 · Chapter 10

Electronegativity Difference — how far do the electrons go?

Pick two elements. The bigger the gap in electronegativity, the further the shared electrons drift toward the stronger atom — until, at the far end, they stop being shared at all. The difference is a number, and the number tells you which kind of bond you have.

Dashed border = metal. Electronegativity values are the one-decimal table used in class.

The difference

Nonpolar covalent
0.0 – 0.4
Polar covalent
0.5 – 1.8
Ionic
1.9 – 3.3
electrons shared
equally
electrons shared
unequally
electrons
transferred

What the electrons do

The class analogy: a crowd on a street drifts toward the more famous person. The cloud is a picture of where the electrons spend their time — there are no percentages on it.

Bonds worked in class

δ⁻ and δ⁺ are partial charges — the electrons leaned over but stayed shared. Full + and − mean they left. That is the whole difference between polar covalent and ionic.